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Excitation Energies and Properties of Open-Shell Singlet Molecules: Applications to a New Class of Molecules for Nonlinear Optics and Singlet Fission … Properties of Atoms, Molecules, and Clusters) by Masayoshi Nakano[PDF]

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Ebook Details


Title: Excitation Energies and Properties of Open-Shell Singlet Molecules: Applications to a New Class of Molecules for Nonlinear Optics and Singlet Fission … Properties of Atoms, Molecules, and Clusters)
Language: English
Year: 2014
Author(s): Masayoshi Nakano
Publisher: Springer
Identifier: 3319081195,9783319081199
Format: pdf
Filesize: 4.1M
Pages: 129
Edition: 2014


Ebook Description


This brief investigates the diradical character, which is one of the ground-state chemical indices for “bond weakness” or “electron correlation” and which allows researchers to explore the origins of the electron-correlation-driven physico-chemical phenomena concerned with electronic, optical and magnetic properties as well as to control them in the broad fields of physics and chemistry. It then provides the theoretical fundamentals of ground and excited electronic structures of symmetric and asymmetric open-shell molecular systems by using model molecular systems. Moreover, it presents the theoretical design guidelines for a new class of open-shell singlet molecular systems for nonlinear optics (NLO) and singlet fission.

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